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Enantiodiscrimination by NMR Spectroscopy

[ Vol. 12 , Issue. 31 ]

Author(s):

Gloria Uccello-Barretta, Federica Balzano and Piero Salvadori   Pages 4023 - 4045 ( 23 )

Abstract:


The analysis of enantiorecognition processes involves the detection of enantiomeric species as well as the study of chiral discrimination mechanisms. In both fields Nuclear Magnetic Resonance (NMR) spectroscopy plays a fundamental role, providing several tools, based on the use of suitable chiral auxiliaries, for observing distinct signals of enantiomers and for investigating the complexation phenomena involved in enantiodiscrimination processes.

Keywords:

Chiral Derivatizing Agents (CDAs),Selenium Reagents,Lanthanide ions,heterocomplexation,diastereoisomers

Affiliation:

, , Dipartimento di Chimica e Chimica Industriale, Universita di Pisa, via Risorgimento 35, 56126 Pisa, Italy.



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